Publications
Independent Publications
55. Campanella, A. J.; Gin, A.; Sung, S.; Jackson, C. E.; Martinez, R.; Ozarowski, A.; Bhowmick, I.; Zadrozny, J. M. “Amplifying the Temperature Sensitivity of Zero-Field Splitting in Mn(II) Through Ligand Tuning” ChemRxiv, 2023. DOI: 10.26434/chemrxiv-2023-hk4dq.
54. Üngor, Ö.; Sanchez, S.; Ozvat, T.; Zadrozny, J. M. “Asymmetry-Enhanced 59Co NMR Thermometry in Co(III) Complexes” Inorg. Chem. Front. 2023, Accepted Manuscript. DOI: 10.1039/D3QI01641B.
53. Martinez, R.; Jackson, C. E.; Üngor, Ö.; van Tol, J.; Zadrozny, J. M. “Impact of Ligand Chlorination and Counterion Tuning on High-Field Spin Relaxation in a Series of V(IV) Complexes” Dalton Trans. 2023, 52, 10805-10816. DOI: 10.1039/D3DT01274C.
52. Kamin, A.; Moseley, I. P.; Oh, J.; Brannan, E.; Gannon, P.; Kaminsky, W.; Zadrozny, J. M.; Xiao, D. J. “Geometry-Dependent Valence Tautomerism, Magnetic Ordering, and Electrical Conductivity in 1D Iron-Tetraoxolene Chains” Chem. Sci. 2023, 14, 4083-4090. DOI: 10.1039/D2SC06392A.
51. Campanella, A. J.; Üngör, Ö.; Zadrozny, J. M. “Quantum Mimicry With Inorganic Chemistry” Comment. Inorg. Chem. 2023, Online article. DOI: 10.1080/02603594.2023.2173588.
50. Üngör, Ö.; Ozvat, T. M.; Grundy, J. V.; Zadrozny, J. M. “Transition-Metal NMR Thermometry” in Comprehensive Inorganic Chemistry III, 2023, Online Manuscript.
49. Üngör, Ö.; Ozvat, T. M.; Ni, Z.; Zadrozny, J. M. “Record Chemical-Shift Temperature Sensitivity in a Series of Trinuclear Cobalt Complexes” J. Am. Chem. Soc. 2022, 144, 9132-9137. DOI: 10.1021/jacs.2c03115. Highlighted by CSU Source! Highlighted by BioIT world!
48. Jackson, C. E.; Negendahimana, T.; Lin, C.-Y.; Eaton, G. R.; Eaton, S. S.; Zadrozny, J. M. “Impact of Counterion Methyl Groups on Spin Relaxation in [V(C6H4O2)3]2-” J. Phys. Chem. C 2022, 126, 7169-7176. DOI: 10.1021/acs.jpcc.2c01090.
47. Torres, J. F.; Oi, C. H.; Moseley, I. P.; El-Sakkout, N.; Knight, B. J.; Shearer, J.; García-Serres, R.; Zadrozny, J. M.; Murray, L. J. “Dinitrogen Coordination to a High Spin Diiron(I/II) Species” Angew. Chem. Int. Ed. 2022, 66, e202202329. DOI: 10.1002/anie.202202329.
46. Moseley, I. P.; Ard, C. P.; DiVerdi, J. A.; Ozarowski, A.; Chen, H.; Zadrozny, J. M. “Slowing Magnetic Relaxation With Open-Shell Diluents” Cell. Rep. Phys. Sci. 2022, 3, 10802. DOI:10.1016/j.xcrp.2022.100802.
45. Campanella, A. J.; Ozvat, T. M.; Zadrozny, J. M. “Ligand Design of Zero-Field Splitting in Trigonal Prismatic Ni(II) Cage Complexes” Dalton Trans. 2022, 51, 3341-3348. DOI:10.1039/D1DT02156G.
44. Ozvat, T. M.; Rappé, A. K.; Zadrozny, J. M. “Isotopomeric Elucidation of the Mechanism of Temperature Sensitivity in 59Co-NMR Molecular Thermometers” Inorg. Chem. 2022, 61, 778-785. DOI: 10.1021/acs.inorgchem.1c03326.
43. Zhao, Y.; Zhu, H.; Wink, D. J.; Sung, S.; Zadrozny, J. M.; Driver, T. G. “Counterion Control of t-BuO-Mediated Single Electron Transfer to Nitrostilbenes Constructs N-Hydroxyindoles or Oxindoles” Angew. Chem. Int. Ed. 2021, 60, 19207-19213. DOI: 10.1002/anie.202104319.
42. Jackson, C. E.; Moseley, I. P.; Martinez, R.; Sung, S.; Zadrozny, J. M. “A Reaction-Coordinate Perspective of Magnetic Relaxation” Chem. Soc. Rev. 2021, 50, 6684-6699. DOI: 10.1039/D1CS00001B.
41. Campanella, A. J.; Nguyen, M.-T.; Zhang, J.; Ngendahimana, T.; Antholine, W. E.; Eaton, G. R.; Eaton, S. S.; Glezakou, V.-A.; Zadrozny, J. M. “Ligand Control of Low-Frequency Electron Paramagnetic Resonance Linewidth in Cr(III) Complexes” Dalton Trans. 2021, 50, 5342-5350. DOI: 10.1039/D1DT00066G.
40. Ozvat, T. M.; Johnson, S. H.; Rappé, A. K.; Zadrozny, J. M. “Ligand Control of 59Co Nuclear-Spin Relaxation Thermometry” Magnetochemistry 2020, 6, 58. DOI: 10.3390/magnetochemistry6040058.
39. Ozvat, T. M.; Sterbinsky, G. E.; Campanella, A. J.; Rappé, A. K.; Zadrozny, J. M. “EXAFS Investigations of Temperature-Dependent Structure in Cobalt-59 Molecular NMR Thermometers” Dalton Trans. 2020, 49, 16380-16385. DOI:10.1039/D0DT01391A. Featured in New Talent: Americas!
38. Johnson, S. H.;§ Jackson, C. E.; Zadrozny, J. M. “Programmable Nuclear Spin Dynamics in Ti(IV) Coordination Complexes” Inorg. Chem. 2020, 59, 7479-7486. DOI: 10.1021/acs.inorgchem.0c00244. §Undergraduate first author. Selected for cover art!
37. Jackson, C. E.; Lin, C.-Y.; van Tol, J.; Zadrozny, J. M. “Orientation Dependence of Phase Memory Relaxation in the V(IV) Ion at High Frequencies” Chem. Phys. Lett. 2020, 739, 137034. DOI: 10.1016/j.cplett.2019.137034.
36. Moseley, I. P.; Lin, C.-Y.; Zee, D. Z.; Zadrozny, J. M. “Synthesis and Magnetic Characterization of a Dinuclear Complex of Low-Coordinate Iron(II)” Polyhedron 2020, 175, 114171. DOI:10.1016/j.poly.2019.114171. Included in a special issue to celebrate MAGNA: Magnetism in North America.
35. Jackson, C. E.; Lin, C.-Y.; Johnson, S. H.; van Tol, J.; Zadrozny, J. M. “Nuclear-Spin-Pattern Control of Electron-Spin Dynamics in a Series of V(IV) Complexes” Chem. Sci. 2019, 10, 8447-8454. DOI: 10.1039/C9SC02899D. Highlighted by the National High Magnetic Field Laboratory!
34. Ozvat, T. M.; Peña, M. E.; Zadrozny, J. M. “Influence of Ligand Encapsulation on Cobalt-59 Chemical-Shift Thermometry” Chem. Sci. 2019, 10, 6727-6734. DOI: 10.1039/C9SC01689A.
33. Lin, C.-Y.; Ngendahimana, T.; Eaton, G. R.; Eaton, S. S.; Zadrozny, J. M. “Counterion Influence on Dynamic Spin Properties in a V(IV) Complex” Chem. Sci. 2019, 10, 548-555. DOI: 10.1039/C8SC04122A.
Postdoctoral Publications
32. Fataftah, M. S.; Krzyaniak, M.; Vlaisavljevich, B.; Wasielewski, M. R.; Zadrozny, J. M.; Freedman, D. E. “Metal–Ligand Covalency Enables Room Temperature Molecular Qubit Candidates” Chem. Sci. 2019, 10, 6707-6714.
31. Zadrozny, J. M.; Gallagher, A. T.; Harris, T. D.; Freedman, D. E. “A Porous Array of Clock Qubits” J. Am. Chem. Soc. 2017, 139, 7089-7094.
30. Graham, M. J.; Zadrozny, J. M.; Fataftah, M. S.; Freedman, D. E. “Forging Solid-State Qubit Design Principles in a Molecular Furnace” Chem. Mater. 2017, 29, 1885-1897.
29. Yu, C.-J.; Graham, M. J.; Zadrozny, J. M.; Niklas, J.; Krzyaniak, M. D.; Wasielewski, M. R.; Poluektov, O. G.; Freedman, D. E. “Long Coherence Times in Nuclear Spin-Free Vanadyl Qubits” J. Am. Chem. Soc. 2016, 138, 14678-14685.
28. Zadrozny, J. M.; Graham, M. J.; Krzyaniak, M. D.; Wasielewski, M. R.; Freedman, D. E. “Unexpected Suppression of Spin-Lattice Relaxation via High Magnetic Field in a High-Spin Iron(III) Complex” Chem. Commun. 2016, 52, 10175-10178.
27. Fataftah, M. S.; Coste, S. C.; Vlaisavljevich, B.; Zadrozny, J. M.; Freedman, D. E. “Transformation of the Coordination Complex [Co(C3S5)2]2– from a Molecular Magnet to a Qubit” Chem. Sci. 2016, 7, 6160-6166.
26. Fataftah, M. S.; Zadrozny, J. M.; Coste, S. C.; Graham, M. J.; Rogers, D. M.; Freedman, D. E. “Employing Forbidden Transitions as Qubits in a Nuclear Spin-Free Chromium Complex” J. Am. Chem. Soc. 2016, 138, 1344-1348.
25. Zadrozny, J. M.; Freedman, D. E. “Qubit Control Limited by Spin-Lattice Relaxation in a Nuclear Spin-Free Iron(III) Complex” Inorg. Chem. 2015, 54, 12027-12031.
24. Zadrozny, J. M.; Niklas, J.; Poluektov, O. G., Freedman, D. E. “Millisecond Coherence Time in a Tunable Molecular Electronic Spin Qubit” ACS Cent. Sci. 2015, 1, 488-492. §Highlighted by ACS Central Science, Daily Mail, and Phys.org!
23. Zadrozny, J. M.; Greer, S. M.; Hill, S.; Freedman, D. E. “A Flexible Iron(II) Complex in which Zero-Field Splitting is Resistant to Structural Variation” Chem. Sci. 2015, 7, 416-423.
22. Zadrozny, J. M.; Niklas, J.; Poluektov, O. G.; Freedman, D. E. “Multiple Quantum Coherences from Hyperfine Transitions in a Vanadium(IV) Complex” J. Am. Chem. Soc. 2014, 136, 15841-15844.
21. Fataftah, M. S.; Zadrozny, J. M.; Rogers, D. M.; Freedman, D. E. “A Mononuclear Transition Metal Single-Molecule Magnet in a Nuclear Spin-Free Ligand Environment” Inorg. Chem. 2014, 53, 10716-10721.
20. Graham, M. J.; Zadrozny, J. M.; Shiddiq, M.; Anderson, J. S.; Fataftah, M.; Hill, S.; Freedman, D. E. “Influence of Electronic Spin and Spin-Orbit Coupling on Decoherence in Mononuclear Transition Metal Complexes” J. Am. Chem. Soc. 2014, 136, 7623-7626. §Highlighted by JACS!
Graduate Publications
19. Craven, M.; Nygaard, M. H.; Zadrozny, J. M.; Long, J. R.; Overgaard, J. “Determination of d-Orbital Populations in a Cobalt(II) Single-Molecule Magnet Using Single-Crystal X-Ray Diffraction” Inorg. Chem. 2018, 57, 6913-6920.
18. Suturina, E. A.; Nehrkorn, J.; Zadrozny, J. M.; Hill, S.; Liu, J.; Atanasov, M.; Weyhermüller, T.; Maganas, D.; Schnegg, A.; Bill, E.; Long, J. R.; Neese, F. “Magneto-Structural Correlations in Pseudo-Tetrahedral [CoII(SPh)4]2- Complexes: Magnetometry, MCD, Advanced EPR and Ab Initio Study” Inorg. Chem. 2017, 56, 3102-3118.
17. Bloch, E. D.; Queen, W. L.; Chavan, S.; Wheatley, P. S.; Zadrozny, J. M.; Morris, R.; Brown, C. M.; Lamberti, C.; Bordiga, S.; Long, J. R. “Gradual Release of Strongly-Bound Nitric Oxide from Fe2(NO)2(dobdc)” J. Am. Chem. Soc. 2015, 137, 3466-3469.
16. Bloch, E. D.; Hudson, M. R.; Mason, J. A.; Chavan, S.; Crocellà, V.; Howe, J. D.; Lee, K.; Dzubak, A. L.; Queen, W. L.; Zadrozny, J. M.; Geier, S. J.; Lin, L.-C.; Gagliardi, L.; Smit, B.; Neaton, J. B.; Bordiga, S.; Brown, C. M.; Long, J. R. “Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in Metal-Organic Frameworks With Exposed Divalent Metal Cations” J. Am. Chem. Soc. 2014, 136, 10752-10761.
15. Demir, S.; Zadrozny, J. M.; Long, J. R. “Large Spin Relaxation Barriers for the Low-Symmetry Organolanthanide Complexes Cp*2Ln(BPh4) (Ln = Tb, Dy)” Chem. Eur. J. 2014, 20, 9524-9529.
14. Zadrozny, J. M.; Xiao, D. J.; Long, J. R.; Atanasov, M.; Neese, F.; Grandjean, F.; Long, G. J. “Mössbauer Spectroscopy as a Probe of Magnetization Dynamics in the Linear Iron(I) and Iron(II) Complexes [Fe(C(SiMe3)3)2]1–/0” Inorg. Chem. 2013, 52, 13123-13131.
13. Maurice, R.; Verma, P.; Zadrozny, J. M., Luo, S.; Borycz, J.; Long, J. R.; Truhlar, D. G.; Gagliardi, L. “Single-Ion Magnetic Anisotropy and Isotropic Magnetic Couplings in the Metal-Organic Framework Fe2(dobdc)” Inorg. Chem., 2013, 52, 9379-9389.
12. Zadrozny, J. M.; Telser, J.; Long, J. R. “Slow Magnetic Relaxation in the Cobalt(II) Complexes [Co(EPh)4]2– (E = O, S, Se)” Polyhedron, 2013, 64, 209-217.
11. Zadrozny, J. M.; Xiao, D. J.; Atanasov, M.; Long, G. J.; Grandjean, F.; Neese, F.; Long, J. R. “Magnetic Blocking in a Linear Iron(I) Complex” Nature Chem. 2013, 5, 577-581. §Highlighted by Nature Chemistry!
10. Forshaw, A. P.; Smith, J. M.; Ozarowski, A.; Krzystek, J.; Smirnov, D.; Zvyagin, D.; Harris, T. D.; Karunadasa, H. I.; Zadrozny, J. M.; Schnegg, A.; Holldack, K.; Jackson, T. A.; Alamiri, A.; Barnes, D. M.; Telser, J. “Low-Spin Hexa-Coordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes” Inorg. Chem. 2013, 52, 144-159.
9. Atanasov, M.; Zadrozny, J. M.; Long, J. R.; Neese, F. “A Theoretical Analysis of Chemical Bonding, Vibronic Coupling, and Magnetic Anisotropy in Linear Iron(II) Complexes with Single Molecule Magnet Behavior” Chem. Sci. 2013, 4, 139-156.
8. Zadrozny, J. M.; Atanasov, M.; Bryan, A. M.; Lin, C.-Y.; Rekken, B. D.; Power, P. P.; Neese, F.; Long, J. R. “Slow Magnetization Dynamics in a Series of Two-Coordinate Iron(II) Complexes” Chem. Sci. 2013, 4, 125-138.
7. Demir, Selvan; Zadrozny, J. M.; Nippe, M.; Long, J. R. “Exchange Coupling and Magnetic Blocking in Bipyrimidyl Radical Bridged Dilanthanide Complexes” J. Am. Chem. Soc. 2012, 134, 18546-18549.
6. Zadrozny, J. M.; Liu, J.; Piro, N. A.; Chang, C. J.; Hill, S.; Long, J. R. “Slow Magnetic Relaxation in a Pseudotetrahedral Cobalt(II) Complex with Easy-Plane Anisotropy” Chem. Commun. 2012, 48, 3927-3939.
5. Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.; Brown, C. M.; Long, J. R. “Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites” Science 2012, 335, 1606-1610.
4. Zadrozny, J. M.; Long, J. R. “Slow Magnetic Relaxation at Zero Field in the Tetrahedral Complex [Co(SPh)4]2-” J. Am. Chem. Soc. 2011, 133, 20732-20734.
3. Zadrozny, J. M.; Freedman, D. E.; Jenkins, D. M.; Harris, T. D.; Iavarone, A. T.; Mathonière, C.; Clérac, R.; Long, J. R. “Slow Magnetic Relaxation and Charge-Transfer in Cyano-Bridged Coordination Clusters Incorporating [Re(CN)7]3-/4-” Inorg. Chem. 2010, 49, 8886-8896.
Undergraduate Publications
2. Tatum, D. S.; Zadrozny, J. M.; Yee, G. T. “A New Family of High Tc Molecule-Based Magnetic Networks: V[x-ClnPTCE]2⋅yCH2Cl2 (PTCE = phenyltricyanoethylene) Magnetochemistry, 2019, 5, 44.
1. Zadrozny, J. M.; “Tunable Three-Dimensional Magnetic Coordination Polymers” Journal of Undergraduate Materials Research (JUMR) 2006, 2, 42-47.